well George Wallace tried to use the National Guard a lil egregiously, although I also think it wasn't desegregated so it was much easier to do so
In today's age? no, those units have older equipment, people are laughably trained in comparison, etc.... They absolutely wouldn't want none from the real Armed Forces. See First Blood when they try to 'get' Rambo in the PNW woods, I know it's a movie, but it's not that far off. The Iowa National Guard guarded our base in Kabul for a bit, they were notorious for falling asleep on duty haha
The worst attack in Kabul when I was there, a VBIED/EFP combo that took out a R&R transport and killed 17 people on board, happened specifically because a National Guard unit had unqualified POGs as gunners, weren't changing their routes, weren't doing proper recon, etc....
it was a cluster